著者

小林 宣男

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.39, no.3, pp.181-191, 1981-03-01 (Released:2009-11-13)

参考文献数

70

被引用文献数

6 5

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This article is concerned with the uses of chiral synthetic polymers as catalysts in asymmetric reactions. The polymer catalysts are classified into two groups : (a) polymers with chiral main chain; (b) polymers with chiral side chain. The asymmetric reactions discussed are hydrocyanation, addition of thiols to C=C, addition of methanol to C=C=O, hydrogenation, Michael reactions, phase-transfer reactions, hydrosilylation, and hydroformylation. The emphasis here will be on the polymer effects.