著者

小野 光則

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.38, no.9, pp.836-852, 1980-09-01 (Released:2009-11-13)

参考文献数

195

被引用文献数

3 3

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Recent progress in regioselective carbon-carbon bond forming reactions involving “ambident substrates” has been reviewed with 308 selected references. This article is divided into two parts, Part 1 concerns the reactions of ambident nucleophiles which mainly include the di-anions of enolates and the asymmetric allylic carbanions. Part 2 involves the reactions of ambident electrophiles which are represented by α, β-unsaturated carbonyl systems, the SN 2' reactions of allylic alcohol derivatives and the epoxy compounds containing a nucleophile in the same molecule. Some plausible explanations and controlling factors of these regioselectivities are summarized.