1 0 0 0 OA 微生物のスクリーニング法I
- 著者
- 新井 守 岡崎 浩
- 出版者
- 公益社団法人 日本農芸化学会
- 雑誌
- 化学と生物 (ISSN:0453073X)
- 巻号頁・発行日
- vol.5, no.5, pp.294-303, 1967-05-25 (Released:2009-05-25)
- 参考文献数
- 24
1 0 0 0 38 Herbicidin A,Bの構造
- 著者
- 寺原 昭 羽石 達生 新井 守 桑野 晴光
- 出版者
- 天然有機化合物討論会実行委員会
- 雑誌
- 天然有機化合物討論会講演要旨集
- 巻号頁・発行日
- vol.18, pp.286-293, 1974
The antifungal metabolite, herbicidin A (C_<23>H_<29>O_<11>N_5) and herbicidin B (C_<18>H_<23>O_9N_5) obtained from Streptmyces saganonensis (Strain No 4075) have a plant growth inhibiting effects against to baryard glass, green panicum, tomato and radish ect., in a concentration 37-300ppm without effect to rice. Basic hydrolysis of herbicidin A affords an unsaturated acid 3 which has been confirmed to be 2-hydroxymethyl-2-butenoic acid, and herbicidin B acid 4. Methanolysis of herbicidin A and B with Amberlyst 15 in methanol affords adenine, and C_<19>H_<28>O_<12> 8 and C_<15>H_<24>O_<10> 5 respectively. On the bases of chemical and physico-chemical evidences of these derivatives, structures of herbicidin A and B have been determined to be nucleosides which consist of adenine and an unusual sugar moiety.