著者

梅野 正行 浜田 三夫

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.38, no.12, pp.1196-1209, 1980-12-01 (Released:2010-01-22)

参考文献数

118

被引用文献数

1

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This article reviews some of recent applications of the Grignard reaction to synthesis of alcohols, ketones, aldehydes, acetals, carboxylic acides, esters, ethers, amino, compounds, organo sulfer compounds, vinyl compounds, acetylenic compounds, and organometalic compounds.A number of compounds produced by the Grignard reaction are very valuable and special intermediates or products in the field of pharmaceutical, perfume, and other fine or specialty chemicals.Synthesis of many optically active compounds by the reaction of sec-alkyl Grignard reagents with alkenyl halides using chiral phosphine-metal complexes as catalysts has been receiving great attention.