著者

高井 千加

出版者

公益財団法人 ホソカワ粉体工学振興財団

雑誌

ホソカワ粉体工学振興財団年報 (ISSN:21894663)

巻号頁・発行日

vol.30, pp.58-64, 2023-05-25 (Released:2023-05-25)

参考文献数

15

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粉体の機能化を図るうえで,粉体の構造と機能を分類することは重要であり,その方法の一つとして機械学習が用いられる.機械学習を材料設計に応用するためには分類精度向上に寄与する因子の“見える化”が重要と考え,原因分析が可能なマハラノビス-タグチ(MT)法を用いることを試みた.モデル粉体材料としてカブトムシ三齢幼虫が排出する糞を対象とし,雌雄分類精度向上に寄与する糞形状が糞の表面粗さに関係する因子であることを明らかにした.雌の糞に含まれるバインダー量が雄のそれより優位に多いことを考慮すると,腸内でプレス成形された糞が体外に排出される際に,雌の糞は形を崩しやすいのではないかと推測される.MT法は,粒子の構造と機能の分類においても,いわゆる個体差に類似したばらつきを除外し,分類精度向上を目指す手法としての展開が期待できる.

著者

藤 正督 ラザヴィ ホソロシャヒ ハディ 高井 千加 佐藤 知広 尾畑 成造 立石 賢司

出版者

一般社団法人 粉体粉末冶金協会

雑誌

粉体および粉末冶金 (ISSN:05328799)

巻号頁・発行日

vol.65, no.10, pp.609-615, 2018-10-15 (Released:2018-11-08)

参考文献数

12

被引用文献数

2 2

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Sintering of most ceramic and composite materials are only possible at temperatures over 1000°C due to their high melting point. Sintering is acknowledged as an expensive process, which takes several hours to several days. In addition, high temperature sintering affects the final product by causing undesired grain coarsening or changing the initial chemical stoichiometry. Our research group has proposed a “non-firing sintering”, where no firing process is required for achieving high densities. The underlying idea of this method involves the chemical activation of powder surface via ball milling, where the surface of particles is rubbed against balls. In this review, we will introduce the mechanism of the method as well as some process know-how, with some examples of preparing solidified bodies of silicon carbide, composite of carbon nanotube (CNT) and silica, and organic/inorganic composite materials.

著者

佐藤 知広 久保田 敦斗 齋藤 賢一 藤 正督 高井 千加 瀬名 ハディ 宅間 正則 高橋 可昌

出版者

公益社団法人 日本材料学会

雑誌

材料 (ISSN:05145163)

巻号頁・発行日

vol.71, no.2, pp.167-174, 2022-02-15 (Released:2022-02-20)

参考文献数

14

被引用文献数

1

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The industrial manufacturing methods for ceramics are powder mixing, molding, and firing. Ceramics are fired at a higher temperature than metal sintering. For this reason, in the ceramics manufacturing process, a large amount of energy is consumed, and a large amount of carbon dioxide is also emitted, especially in the firing process. Therefore, attention is focused on the non-firing solidification process of ceramics. In this method, after the molding process, there is a solidification process using a solvent instead of firing. In order to realize this solidification process, a grinding process is required to increase the activation energy of the surface of the raw ceramics particle. Therefore, in this study, we set up a molecular dynamics model that simulated grinding and calculated the activation of the silica surface. The grinding of the material surface was modified by the cylindrical indenter of LAMMPS, the material surface was constantly activated by passing multiple indenters continuously instead of a single indenter. As a result, a clear increase in energy was observed. It was suggested that continuous energy input is more effective than local energy input to the surface when reproducing surface activity. Furthermore, activation of the internal structure was observed as in the experiment. Adding water molecules in the relaxation calculation on the activated surface, binding through and without water molecules was observed. It was clarified that there are hydrogen bonds and siloxane bonds in this bond.