- 著者
- Ildikó V. TÓTH Inês C. SANTOS Cláudia F. M. AZEVEDO Jorge F. S. FERNANDES Ricardo N. M. J. PÁSCOA Raquel B. R. MESQUITA António O. S. S. RANGEL
- 出版者
- (社)日本分析化学会
- 雑誌
- Analytical Sciences (ISSN:09106340)
- 巻号頁・発行日
- vol.29, no.5, pp.563-570, 2013-05-10 (Released:2013-05-10)
- 参考文献数
- 30
- 被引用文献数
- 3 5
In this work, aiming to develop a simple, inexpensive method for the determination of low bromate levels in water samples, a liquid waveguide capillary cell (LWCC) was coupled to a FIA system. The long optical path (100 cm) of the LWCC was used to improve the sensitivity and the limit of detection without resorting to any off-line or in-line preconcentration processes. The spectrophotometric determination was based on the oxidation of chlorpromazine by bromate in an acidic medium, resulting in the formation of a colored radical product. Sulfamic acid was added to the reagent for minimizing the interference of nitrite, and a chelating ion exchange resin was used to remove major cationic interferences. The developed system allowed the determination of bromate within the range between 1 – 20 μg L−1 with a detection limit of 0.2 μg L−1.