- 著者
- Yuma MORIMITSU Yohei SHIROSE Satomi ENJU Kenji TSURUTA Norimasa SHIMOBAYASHI
- 出版者
- Japan Association of Mineralogical Sciences
- 雑誌
- Journal of Mineralogical and Petrological Sciences (ISSN:13456296)
- 巻号頁・発行日
- pp.201130d, (Released:2021-04-27)
Zaïrite was found from the quartz vein penetrating into the metamorphosed mudstone of the Wazuka Unit in Ishidera area, Wazuka–cho, Kyoto Prefecture, Japan, which is the first occurrence in Japan. Zaïrite occurs as bright–yellow granular crystals (20–30 µm) in a cavity formed by the leaching of fluorapatite with native bismuth inclusion. The chemical composition of zaïrite from Ishidera was closer to the ideal chemical composition, comparing with the zaïrite from type locality including Al. The empirical formula from electron probe microanalyzer (EPMA) analysis on the basis of O = 8, OH− = 6 was (Bi0.70Ca0.23)Σ0.93Fe3+2.91(P2.04S0.09O8)(OH)6. The unit cell parameters obtained from the X–ray diffraction (XRD) pattern were a = 7.311(3) Å and c = 16.407(7) Å, larger than the type locality due to difference in chemical composition.
- 著者
- Kenji Tsuruta Hiroyuki Yamamoto Masanori Katsuyama Yoshiko Kosugi Motonori Okumura Naoko Matsuo
- 出版者
- 水文・水資源学会/日本地下水学会/日本水文科学会/陸水物理研究会
- 雑誌
- Hydrological Research Letters (ISSN:18823416)
- 巻号頁・発行日
- vol.13, no.1, pp.1-6, 2019 (Released:2019-02-02)
- 参考文献数
- 32
- 被引用文献数
- 14
Cryogenic vacuum distillation (CVD) methods have been widely used to extract water from unsaturated soil materials. However, recent studies have reported that extraction conditions (e.g. extraction time) and soil type can influence the stable isotope ratios of soil water extracted by CVD. We examined (i) the effects of extraction time on the stable isotope ratios of soil water extracted by CVD, and (ii) how the stable isotope ratios differed from those of soil water extracted by other methods. We first examined extraction times of 1–6 h, and observed no significant differences in the δ2H or δ18O values of extracted soil water for extraction times >2 h. However, extraction for 1 h collected only 48% of soil water, and the δ2H and δ18O values were significantly lower than those for extraction times >2 h. We then compared the stable isotope ratios of soil water extracted by CVD and centrifugation. Although the stable isotope ratios for both extraction methods were within the range of that of rainwater, the stable isotope ratios for water extracted by CVD were lower than those for water extracted by centrifugation. Our results highlight questions surrounding the use of CVD for stable isotope analysis of soil water.