著者

Koji Yoshimoto Takeshi Yatabe Takahiro Matsumoto Andrew Robertson Hidetaka Nakai Hiromasa Tanaka Takashi Kamachi Yoshihito Shiota Kazunari Yoshizawa Koichiro Asazawa Hirohisa Tanaka Seiji Ogo

出版者

(社)日本化学会

雑誌

Chemistry Letters (ISSN:03667022)

巻号頁・発行日

vol.45, no.2, pp.149-151, 2016-02-05 (Released:2016-02-05)

参考文献数

44

被引用文献数

4

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We report the first example of a µ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N≡N stretching vibration has been observed at 1994 cm−1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N≡N bond is primed for activation.