- 著者
-
Takanori Suzuki
Takuma Kuroda
Hitomi Tamaoki
Sho Higasa
Ryo Katoono
Kenshu Fujiwara
Takanori Fukushima
Hidetoshi Yamada
- 出版者
- (社)日本化学会
- 雑誌
- Chemistry Letters (ISSN:03667022)
- 巻号頁・発行日
- vol.42, no.7, pp.706-708, 2013-07-05 (Released:2013-07-05)
- 参考文献数
- 29
Upon oxidation of the title heterocycles with dimethylamino groups, elemental sulfur is extruded to form dicationic dyes, which regenerate the heterocycles by the reaction with Na2S. The electrolysis of the heterocycles induces a drastic change in UV–vis spectrum exhibiting several isosbestic points. The bay-region substituents enhance configurational stability, so the optically pure heterocycle can be obtained in terms of helicity of one-handedness, and its chromism is accompanied by a large chiroptical response as detected by CD spectroscopy.