著者

Toshihiro Tsuchiyama Kurato Inoue Katsutoshi Hyodo Daichi Akama Nobuo Nakada Setsuo Takaki Tamotsu Koyano

出版者

The Iron and Steel Institute of Japan

雑誌

ISIJ International (ISSN:09151559)

巻号頁・発行日

vol.59, no.1, pp.161-168, 2019-01-15 (Released:2019-01-17)

参考文献数

37

被引用文献数

9 16

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The microstructure and hardness of martensite in Fe–C and Fe–N alloys with up to 7.5 at% contents of carbon and nitrogen, respectively, were compared. Their difference in hardness was discussed based on four strengthening mechanisms. The martensitic structures of Fe–C and Fe–N alloys with equal contents of carbon and nitrogen, respectively, were nearly identical, except for the amount of retained austenite. Furthermore, Fe–C alloy was considerably harder than Fe–N alloy. This discrepancy gradually increased with carbon and nitrogen contents. The enhanced hardness of Fe–C alloy martensite was attributed to its higher dislocation density and the stronger pinning force of interstitial carbon atoms on dislocations.

著者

Nobuo Nakada Norihide Fukuzawa Toshihiro Tsuchiyama Setsuo Takaki Tamotsu Koyano Takashi Iwamoto Yasuhiro Omori

出版者

The Iron and Steel Institute of Japan

雑誌

ISIJ International (ISSN:09151559)

巻号頁・発行日

vol.53, no.1, pp.139-144, 2013 (Released:2013-01-15)

参考文献数

22

被引用文献数

10 13

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In order to understand the mechanism of isothermal transformation of Fe–N alloy, the isothermal transformation microstructure that forms in a wide temperature range below Ae1 was investigated in Fe–2.6 mass%N hypereutectoid alloy by means of the electron back scatter diffraction method in addition to the conventional microstructural observation methods. High-nitrogen austenite fully decomposed to ferrite and Fe4N over the entire temperature range, and the time-temperature-transformation (TTT) diagram had a C shape with a nose temperature around 700 K. The hardness linearly increased with decreasing transformation temperature because the microstructure became finer, but the morphology of the (ferrite + Fe4N) structure changed discontinuously at around 800 K. From the microstructural and crystallographic analyses, it was concluded that the microstructure formed at higher temperature is a lamellar eutectoid structure, braunite, while the other is an upper bainitic structure containing bainitic ferrite formed through a displacive mechanism and Fe4N formed by concentration and ordering of the nitrogen. Since Fe4N is a counterpart of the cementite in Fe–C alloy, the respective structures are similar to pearlite and upper bainite in carbon steel.