著者

大久保 光 坪井 涼 田所 千治 佐々木 信也

出版者

一般社団法人 日本機械学会

雑誌

日本機械学会論文集 (ISSN:21879761)

巻号頁・発行日

vol.81, no.824, pp.14-00656-14-00656, 2015 (Released:2015-04-25)

参考文献数

12

被引用文献数

1 5

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This research studied the effects of Zinc Dialkyldithiophosphate (ZnDTP) additives on the tribological properties of a H-free Diamond-like Carbon (DLC) film under boundary lubrication with oils that contained organic friction modifiers (FMs). The tribological properties were evaluated using the reciprocating type cylinder-on-disk tribo-tester. ZnDTP and three types of organic additives (GMO, glycerol mono-oleoyl ether (GME), and tallow diethanol amine (TDEA)) were added to poly-alpha olefin (PAO). Friction tests were carried out for the DLC/Steel tribo-pair under lubrication with PAO and PAO-based oils containing GMO, GME, TDEA, ZnDTP, GMO + ZnDTP, GME + ZnDTP, and TDEA + ZnDTP additives. Raman spectroscopy, Scanning Electron Microscopy (SEM), energy-dispersive X-ray analysis (EDX) and X-ray photoelectron spectroscopy (XPS) were used for analyses of worn surface on the H-free DLC film. The H-free DLC film lubricated with PAO + FMs reached an ultralow friction coefficient of 0.02 - 0.03. On the other hand, The H-free DLC film lubricated with PAO + FMs + ZnDTP had increased friction coefficients compared to the PAO + FMs oils. For the lubrication added ZnDTP additive, the surface analyses demonstrated that the chemical composition of the ZnDTP-derived tribofilm depended on the combination of ZnDTP and each FM. It was concluded that the chemical composition of the ZnDTP-derived tribofilm played an important role in the friction behavior of the H-free DLC films that were lubricated with PAO + ZnDTP and PAO + FMs + ZnDTP.