著者

森川 理 大竹 貫洋 埴 英郎 松村 光明 三浦 宏之 高橋 英和 西村 文夫 本橋 孝志

出版者

社団法人 日本補綴歯科学会

雑誌

日本補綴歯科学会雑誌 (ISSN:03895386)

巻号頁・発行日

vol.46, no.2, pp.213-222, 2002-04-10 (Released:2010-08-10)

参考文献数

19

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目的: 口腔内で使用する合金は生体適合性に優れ, 各種修復物に応用可能なものが望まれる. 最近, 耐食性に優れ, 生体適合性も良いとされる歯科用金チタン合金が市販された. そこで, この合金の機械的性質および陶材との焼付強さを測定し, その有用性を検討した.方法: 実験には市販の陶材焼付用金チタン合金を使用した. 各種鋳造試験片はメーカーの指示に従って鋳造, 熱処理を行い作製した. 機械的特性として引張特性, 硬さを, 熱的特性として熱膨張係数を測定した. 金チタン合金と従来型陶材, 超低溶陶材との焼付強さをDIN13927に準じて求めた. 対照として, 従来の陶材焼付用金合金と従来型陶材の焼付強さも求めた. 金チタン合金に従来型陶材を築盛し割断した試料をEPMA分析した.結果: 引張特性と硬さは熱処理により変化し, 軟化熱処理した値は有意に小さかった. 硬化熱処理ではタイプ4金合金に近い機械的性質を示した. 熱膨張係数は従来の陶材焼付用金合金よりも大きかった. 焼付強さはいずれの陶材を用いても40MPa以上を示し, 従来型陶材焼付用金合金の値とは有意な差を認めなかった. 剥離面を観察したところ金属側には陶材の成分が, 陶材側にはチタンが存在していた.割断面を観察したところ, 焼付界面直下に酸化チタンが認められた.結論: 今回検討した金チタン合金は, 単一合金で広範囲な修復が可能な機械的性質を有し, かつ十分な焼付強さを示したことからその有用性が示唆された.

著者

埴 英郎

出版者

口腔病学会

雑誌

口腔病学会雑誌 (ISSN:03009149)

巻号頁・発行日

vol.60, no.3, pp.372-397, 1993 (Released:2010-10-27)

参考文献数

72

被引用文献数

1

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In order to study the changes of the intraoral metals, the surface condition and composition of the crowns removed from mouths were analyzed by SEM and EPMA. Thirty-four samples were categorized into four types of alloys. Corrosive changes were evaluated by comparing the analysis results between the crown surface and its fresh sectioned surface, and also with the data from former studies. 1. Changes observed in the Au alloys were slight compared to the other three types, both in surface feature and composition, except for a slight decreace in Cu. 2. In some Au-Ag-Pd alloys, nearly no dissolution was evident. Composition changes were small, with a slight decrease in Ag and relative increase in Pd. 3. The greatest changes were observed in the Ag-Sn-Zn alloys and Ag-In alloys, even with short intraoral usage period. Generally, their surfaces were rough, with thick layers of organic materials. The dendritic structure was distinct, and dissolution between each dendrite was observed. 4. Many of the Ni-Cr alloys presented dendritic structure with dissolution. Decrease in Ni and relative increase in Si and Cr were observed. 5. Corrosive changes showed a close resemblance to the results obtained by the conven-tional basic tests. However, there were some features which did not coincide, depending on the types of alloys.

著者

濱野 英也 魚島 勝美 苗 維平 益田 高行 松村 光明 埴 英郎 北崎 祐之 井上 昌幸

出版者

口腔病学会

雑誌

口腔病学会雑誌 (ISSN:03009149)

巻号頁・発行日

vol.65, no.1, pp.93-99, 1998-03-31 (Released:2010-10-08)

参考文献数

12

被引用文献数

7 11

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Allergies caused by metals have been increasing. The number of patients visiting dentists with the chief complaint of metal allergy has also been increasing. From March 1994 to February 1997, 263 patients who complained of various symptoms visited our allergy clinic. Among them, 184 patients were suspected to have allergy caused by metals in dental restoration materials and were referred to the patch test. Among 165 patients', 128 were positives for metal allergy. Constituent elements of intraoral metals were analyzed in 107 of these 128 positive patients. The findings were as follows:1. The most common five elements acting on the patients were Hg, Co, Ni, Cr, and Pd.2. The most frequently used elements of dental restoration metal materials were Zn, Ag, Cu, Au, and Pd, and the alloy was Au-Ag-Pd alloy.3. The highest tendency of coincidence between allergen and intraoral metals were observed among Co-Cr-Ni alloys and Pd, Ni, and Cr elements.4. In case of palmoplantar pustulosis, allergen metals tended to be the same as intraoral metal elements.