著者
忍久保 洋 大蔦 幸一郎
出版者
The Society of Synthetic Organic Chemistry, Japan
雑誌
有機合成化学協会誌 (ISSN:00379980)
巻号頁・発行日
vol.57, no.1, pp.13-23, 1999-01-01 (Released:2009-11-16)
参考文献数
26
被引用文献数
8 10

Two types of reactions with organomanganese have been examined. The first is a reaction of manganate reagents with carbon-carbon multiple bond. Catalytic version of these reactions is also disclosed. The second is a reaction of gem-dibromo compounds such as gem-dibromocyclopropane and dibromomethyltrialkylsilane with trialkylmanganate (II). The reaction was initiated by bromine-manganese exchange.