著者

忍久保 洋 大蔦 幸一郎

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.57, no.1, pp.13-23, 1999-01-01 (Released:2009-11-16)

参考文献数

26

被引用文献数

8 10

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Two types of reactions with organomanganese have been examined. The first is a reaction of manganate reagents with carbon-carbon multiple bond. Catalytic version of these reactions is also disclosed. The second is a reaction of gem-dibromo compounds such as gem-dibromocyclopropane and dibromomethyltrialkylsilane with trialkylmanganate (II). The reaction was initiated by bromine-manganese exchange.