2 0 0 0 OA 小室家の中世文書 : 「屋代典憲氏所蔵古文書之写」について
1 0 0 0 OA シロキシフランおよびシロキシオキサゾールを用いる合成反応
- 著者
- 浅岡 守夫 武井 尚
- 出版者
- The Society of Synthetic Organic Chemistry, Japan
- 雑誌
- 有機合成化学協会誌 (ISSN:00379980)
- 巻号頁・発行日
- vol.41, no.8, pp.718-727, 1983-08-01 (Released:2009-11-13)
- 参考文献数
- 41
- 被引用文献数
- 2 3
This article describes carbon-carbon bond forming reactions utilizing trialkylsiloxy substituted heterocyclic aromatic compounds and their synthetic applications. Siloxyfurans synthesized from buten-4-olides or succinic anhydrides reacted with dienophiles to give corresponding Diels-Alder adducts. In the presence of Lewis acids they also reacted with orthoesters, acetals, α, β-unsaturated ketones, aldehydes, and ketones to give corresponding buten-4-olide derivatives or bislactones.Similar reactions of siloxyoxazoles synthesized from 2-oxazolin-5-ones are also described.