著者

浅岡 守夫 武井 尚

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.41, no.8, pp.718-727, 1983-08-01 (Released:2009-11-13)

参考文献数

41

被引用文献数

2 3

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This article describes carbon-carbon bond forming reactions utilizing trialkylsiloxy substituted heterocyclic aromatic compounds and their synthetic applications. Siloxyfurans synthesized from buten-4-olides or succinic anhydrides reacted with dienophiles to give corresponding Diels-Alder adducts. In the presence of Lewis acids they also reacted with orthoesters, acetals, α, β-unsaturated ketones, aldehydes, and ketones to give corresponding buten-4-olide derivatives or bislactones.Similar reactions of siloxyoxazoles synthesized from 2-oxazolin-5-ones are also described.