著者
生越 久靖 青山 安宏
出版者
The Society of Synthetic Organic Chemistry, Japan
雑誌
有機合成化学協会誌 (ISSN:00379980)
巻号頁・発行日
vol.39, no.11, pp.1028-1038, 1981-11-01 (Released:2009-11-13)
参考文献数
69
被引用文献数
1

Recent advances in the biomimetic chemistry of metal complexes of porphyrins and related compounds are briefly reviewed. Selected topics include (i) higher valent oxometalloporphyrins with relevance to the proposed intermediates in the enzymatic reactions of cytochrome P450, peroxidase, and catalase, (ii) myoglobin and hemoglobin models to elucidate the possible protein control of heme reactivities, and (iii) some novel redox behaviors of metalloporphyrins and related compounds. Some clinical chemistry of chlorophyll derivatives are also described.