著者

矢野 裕太

出版者

名古屋大学

巻号頁・発行日

2020

著者

伊藤 英人 矢野 裕太 伊丹 健一郎

出版者

化学同人

雑誌

化学 = Chemistry (ISSN:04511964)

巻号頁・発行日

vol.75, no.6, pp.39-44, 2020-06

著者

伊藤 英人 松岡 和 矢野 裕太 柴田 万織 伊丹 健一郎

出版者

公益社団法人 有機合成化学協会

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.78, no.7, pp.671-682, 2020-07-01 (Released:2020-07-09)

参考文献数

63

被引用文献数

1 1

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Polycyclic aromatic compounds are recognized as highly important class of compounds in materials science due to their high utility as organic semiconductors and organic optoelectronic materials. In general, they can be obtained through the established π-extension methods from unfunctionalized aromatics, while the syntheses are often suffered from multi-step process including halogenation, coupling reaction, Diels-Alder reaction, aromatization and so on. Recently, we have established a novel synthetic concept “annulative π-extension (APEX)” which has the potential to have a tremendous impact on the fields of synthetic chemistry since it allows rapid access to fused aromatic systems from simple unfunctionalized aromatic compounds in a single step. Here we report our recent results of palladium-catalyzed APEX reactions for the synthesis of polycyclic aromatic hydrocarbons, polycyclic heteroaromatics, nanographenes and even graphene nanoribbons from readily available unfunctionalized aromatics.

著者

Yano Yuuta 矢野 裕太

出版者

名古屋大学

巻号頁・発行日

2020-03-25