4 0 0 0 OA 催涙剤成分イソチオシアン酸アリルとアルコールとの反応
- 著者
- 金森 美江子 野口 絵里子 金森 達之 大森 毅 瀬戸 康雄
- 出版者
- 日本法科学技術学会
- 雑誌
- 日本法科学技術学会誌 (ISSN:18801323)
- 巻号頁・発行日
- vol.16, no.2, pp.145-151, 2011 (Released:2011-08-12)
- 参考文献数
- 12
- 被引用文献数
- 2 2
We ascertained that one of the lachrymator, allyl isothiocyanate (AITC), reacted with alkyl alcohol to form O-alkyl allylthiocarbamate. AITC was incubated with methanol, ethanol (EtOH) or 2-propanol, respectively, and analyzed by gas chromatography/mass spectrometry (GC/MS). On the total ion chromatogram of the reaction mixture, one peak appeared which was different from AITC, and the molecular weight was 131, 145 or 159, respectively. The reaction product of AITC with EtOH was prepared from the mixture. By 1H nuclear magnetic resonance (NMR) analysis, six pairs of the signals which resembled each other appeared at room temperature and some of the paired signals overlapped by heating. It was suggested that the reaction product of AITC with EtOH was O-ethyl allylthiocarbamate, and that it was composed of the mixture of conformational isomers at room temperature.
1 0 0 0 OA 化学兵器用剤のガスクロマトグラフィー質量分析
- 著者
- 瀬戸 康雄 井浦 一光 金森 美江子
- 出版者
- 日本法科学技術学会
- 雑誌
- 日本法科学技術学会誌 (ISSN:18801323)
- 巻号頁・発行日
- vol.10, no.1, pp.49-61, 2005 (Released:2007-12-10)
- 参考文献数
- 20
- 被引用文献数
- 5 5
Gas chromatographic mass-spectrometric analysis was performed for chemical warfare agents and related compounds including sarin, soman, tabun, VX, mustard gas, lewisite 1, 2-chloroacetophenone, o-chlorobenzilidenemalononitrile and capsaicin, under electron ionization and methane chemical ionization conditions using apolar and polar capillary columns. It was possible to identify the tested compounds with respects to their retention indices and mass spectra. Under the analytical conditions of split ratio (50:1), electron ionization and scan mode data aquisition, the limit of detection ranged from 0.06 to 7 μg/ml, except for the low detection sensitivity of lewisite 1.