著者
Masaru Yamasaki Takayuki Ishida
出版者
(社)日本化学会
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
vol.44, no.7, pp.920-921, 2015-07-05 (Released:2015-07-05)
参考文献数
25
被引用文献数
21

A novel dinuclear iron(II) complex [{Fe(py3COH)(NCS)(μ-NCS)}2](PrOH)2 was prepared. Each Fe ion is coordinated with three N atoms from tridentate tris(2-pyridyl)methanol (py3COH) and two N and one S atoms from NCS− coligand. It showed a one-step gradual spin-crossover at T1/2 = 207 K. This compound is the first spin-crossover material having an FeN5S coordination structure.