- 著者
-
Masaru Yamasaki
Takayuki Ishida
- 出版者
- (社)日本化学会
- 雑誌
- Chemistry Letters (ISSN:03667022)
- 巻号頁・発行日
- vol.44, no.7, pp.920-921, 2015-07-05 (Released:2015-07-05)
- 参考文献数
- 25
A novel dinuclear iron(II) complex [{Fe(py3COH)(NCS)(μ-NCS)}2](PrOH)2 was prepared. Each Fe ion is coordinated with three N atoms from tridentate tris(2-pyridyl)methanol (py3COH) and two N and one S atoms from NCS− coligand. It showed a one-step gradual spin-crossover at T1/2 = 207 K. This compound is the first spin-crossover material having an FeN5S coordination structure.