- 著者
-
Shoko Suzuki
Ryota Sakamoto
Hiroshi Nishihara
- 出版者
- (社)日本化学会
- 雑誌
- Chemistry Letters (ISSN:03667022)
- 巻号頁・発行日
- vol.42, no.1, pp.17-18, 2013-01-05 (Released:2012-12-22)
- 参考文献数
- 23
- 被引用文献数
-
3
[Ru(tpy)(picSO)]BF4 (tpy: 2,2′:6′,2′′-terpyridine, picSO: 6-[(methylsulfinyl)methyl]picolinate) undergoes profound linkage isomerization behavior between stable S-bound and metastable O-bound isomers. S-[RuII(tpy)(picSO)]BF4 experiences photoisomerization to O-[RuII(tpy)(picSO)]BF4 upon irradiation with 436 nm light, whereas the back reaction is triggered with 546 nm light. Electrochemical linkage isomerization also takes place.