著者

Toshitaka Gamo Harue Masuda Toshiro Yamanaka Kei Okamura Junichiro Ishibashi Eiichiro Nakayama Hajime Obata Kiminori Shitashima Yoshiro Nishio Hiroshi Hasumoto Masaharu Watanabe Kyohiko Mitsuzawa Nobukazu Seama Urumu Tsunogai Fumitaka Kouzuma Yuji Sano

出版者

GEOCHEMICAL SOCIETY OF JAPAN

雑誌

GEOCHEMICAL JOURNAL (ISSN:00167002)

巻号頁・発行日

vol.38, no.6, pp.527-534, 2004-12-20 (Released:2008-04-08)

参考文献数

31

被引用文献数

12 32

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This paper reports a series of studies leading to the discovery of a submarine hydrothermal field (called Nakayama Field) at an arc seamount (12°43′N, 143°32′E) in the southernmost part of the Mariana Trough, western Pacific Ocean. We first detected hydrothermal plumes characterized by water column anomalies of temperature, light transmission, Mn, Fe, Al, O2, CH4, and δ13C of CH4 above the summit caldera of the seamount. Then deep-tow camera surveys confirmed the existence of hydrothermal activity inside the caldera, and an ROV dive finally discovered white smoker-type fluid venting associated with vent fauna. A high concentration of aluminum in the plume and white smoker-type emissions imply acidic hydrothermal activity similar to that observed at the DESMOS Caldera in the eastern Manus Basin, Papua New Guinea. Anomalously low δ13C (CH4) of −38‰ of a vent fluid sample compared to other arc hydrothermal systems along the Izu-Bonin and Mariana Arcs suggests an incorporation of biogenic methane based on a subsurface microbial ecosystem.

著者

Tomohiro Toki Kiichiro Kawamura Urumu Tsunogai Toshitaka Gamo

出版者

Japan Agency for Marine-Earth Science and Technology

雑誌

JAMSTEC Report of Research and Development (ISSN:18801153)

巻号頁・発行日

vol.25, pp.1-12, 2017-09-01 (Released:2017-09-28)

参考文献数

39

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We describe in detail the pore water chemistry in the sediments below a white mat around a bunch of bananas at a water depth of 2,200 m in the Tenryu Submarine Canyon. We infer the metabolism of microbes in the sediments around the bananas based on the chemical and isotopic compositions of the pore water. On the basis of the relation between ammonia and total carbonate (ΣCO2) concentrations in the pore water, we identified that an excess ΣCO2 was distributed around the bananas that cannot be explained by the decomposition of organic matter derived from marine organisms, indicating that the bananas decomposed to generate the excess ΣCO2. We conclude that the bananas built a local organic-rich environment, stimulating the activity of organotrophic bacteria.

著者

SHINSUKE KAWAGUCCI KOTARO SHIRAI TEFANG FAITH LAN NAOTO TAKAHATA URUMU TSUNOGAI YUJI SANO TOSHITAKA GAMO

出版者

GEOCHEMICAL SOCIETY OF JAPAN

雑誌

GEOCHEMICAL JOURNAL (ISSN:00167002)

巻号頁・発行日

vol.44, no.6, pp.507-518, 2010-12-20 (Released:2013-03-23)

参考文献数

60

被引用文献数

14 35

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Hydrothermal plumes above the HAKUREI and JADE sites, two high-temperature hydrothermal vent sites in the Izena Cauldron at the mid-Okinawa Trough, were investigated in order to gain a preliminary understanding of gas geochemical characteristics at underlying hydrothermal vent sites. Three geochemical tracers, H2, CH4 and δ3He, covary with each other above the HAKUREI site but only CH4 and δ3He are correlated above the JADE site. The carbon isotope ratio of methane within the Izena Cauldron can be accounted by a combination of the fluid dilution by ambient seawater and microbial consumption with the kinetic carbon isotope effect (KIE) of 1.007. An estimated endmember δ13C value of -32‰ in the HAKUREI fluid was obtained. Both the plumes above the HAKUREI and JADE sites showed C1/C2 ratios between 103∼104. Only the bottom water around the HAKUREI site showed significant N2O excess with isotopically light δ15N and δ18O, suggesting N2O input from microbial activity in the sediment. A linear correlation between H2 and CH4 in the HAKUREI plume gives a H2/CH4 ratio of the HAKUREI fluid of more than 0.022. The estimated H2/CH4 ratio in the HAKUREI fluid is significantly higher than that of the JADE fluid, comparable with those of fluids venting at other sediment-related hydrothermal systems, and also comparable with those of thermogenic gases produced by hydrothermal sediment experiments. These facts suggest that fluid-sediment interaction during fluid upwelling appears to modify gas geochemical characteristics at the HAKUREI site but have little influence at the JADE site. This study demonstrates the availability of the Izena Cauldron hydrothermal field and the HAKUREI and JADE sites as a natural laboratory for investigating the fluid-sediment interaction during fluid upwelling.

著者

M. Lutfi FIRDAUS Ikka FITRIANI Santhy WYANTUTI Yeni W. HARTATI Renat KHAYDAROV Jason A. MCALISTER Hajime OBATA Toshitaka GAMO

出版者

The Japan Society for Analytical Chemistry

雑誌

Analytical Sciences (ISSN:09106340)

巻号頁・発行日

vol.33, no.7, pp.831-837, 2017-07-10 (Released:2017-07-10)

参考文献数

60

被引用文献数

2 95

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Novel green-chemistry synthesis of silver nanoparticles (AgNPs) is introduced as a low-cost, rapid and easy-to-use analytical method for mercury ion detection. Aqueous fruit extract of water apple (Syzygium aqueum) was used for the first time as bioreductant to synthesize stable AgNPs. The prepared AgNPs have a yellowish-brown color with a surface plasmon resonance peak at 420 nm. The addition of Hg(II) ions then changes the AgNPs color to colorless. The color change was in proportion to the concentration of Hg(II) ions. The presence of other metal ions in the system was also evaluated. The proposed method shows good selectivity and sensitivity towards Hg(II) ions. Using UV-visible spectrophotometry, the detection limit of the developed method was 8.5 × 10−7 M. The proposed method has been successfully applied for determination of Hg(II) ions in tap and lake water samples with precision better than 5%.

著者

Toshitaka GAMO Kiminori SHITASHIMA

出版者

The Japan Academy

雑誌

Proceedings of the Japan Academy, Series B (ISSN:03862208)

巻号頁・発行日

vol.94, no.1, pp.45-55, 2018-01-11 (Released:2018-01-11)

参考文献数

35

被引用文献数

9

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Vertical profiles of potential temperature, salinity, and some chemical components were obtained at a trench station (29°05′N, 142°51′E; depth = 9768 m) in the Izu-Ogasawara (Bonin) Trench in 1984 and 1994 to characterize the hadal waters below ∼6000 m depth. We compared portions of both the 1984 and 1994 profiles with nearby data obtained between 1976 and 2013. Results demonstrated that the hadal waters had slightly higher potential temperature and nitrate and lower dissolved oxygen than waters at sill depths (∼6000 m) outside the trench, probably due to the effective accumulation of geothermal heat and active biological processes inside the trench. The silicate, iron, and manganese profiles in 1984 showed slight but significant increases below ∼6000 m depth, suggesting that these components may have been intermittently supplied from the trench bottom. Significant amounts of 222Rn in excess over 226Ra were detected in the hadal waters up to 2675 m from the bottom, reflecting laterally supplied 222Rn from the trench walls.

著者

Toshitaka GAMO Kei OKAMURA Kyohiko MITSUZAWA Kenichi ASAKAWA

出版者

The Japan Academy

雑誌

Proceedings of the Japan Academy, Series B (ISSN:03862208)

巻号頁・発行日

vol.83, no.7, pp.199-204, 2007-07-30 (Released:2007-11-02)

参考文献数

29

被引用文献数

5 9

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We successfully deployed an in situ automatic chemical analyzer sensitive to manganese (Mn) in seawater for a period of 81 days for the first time on the deep seafloor of Sagami Bay along a convergent plate boundary south of Japan. The in situ Mn analyzer (GAMOS-IV) was connected to a submarine cable as a means to supply power and to relay real time data. During the observation period from April 5 till June 25, 2006, the amount of measured Mn was seen to increase abruptly up to 10 times that of the background level only on April 21, probably triggered by a M5.8 earthquake which occurred ∼7 km south-southwest of the observation site. This study demonstrates the suitability of submarine cables for the long-term geochemical monitoring of deep sea environments.(Communicated by Taroh MATSUNO, M.J.A.)