著者

細見 彰

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.40, no.6, pp.545-553, 1982-06-01 (Released:2009-11-13)

参考文献数

62

被引用文献数

5 7

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Iodotrimethylsilane which has a hard acid (Me3Si) -soft base (I) bond displays a strong oxygenophilicity towards ethers, esters, lactones, acetals, and other molecules involving oxygen atom as a functional group. Recent progress of the chemistry of iodotrimethylsilane is reviewed especially from a view point of organic synthesis. The application of bromotrimethylsilane to organic synthesis is also discussed briefly.