著者

Akira TAKASU Yasumitsu SUZUKI Yoshiya OHKI Takahiko OGAWARA Shizue SETO (SAKAMOTO)

出版者

The Association for the Geological Collaboration in Japan

雑誌

地球科学 (ISSN:03666611)

巻号頁・発行日

vol.76, no.1, pp.37-42, 2022-01-25 (Released:2022-06-25)

参考文献数

26

---

Kosmochlor-bearing eckermannite rock is identified in the Yamanobo outcrop of Itoigawa City, Niigata Prefecture, Japan, which is emplaced within a serpentinite body of the Renge metamorphic belt. The eckermannite rock is likely a large enclave within the serpentinite body, with an albitite zone developed between the eckermannite rock and serpentinite matrix. Kosmochlor is lens-shaped or schlieren-like domains within the eckermannite matrix, and comprises spherical aggregates of radiated kosmochloric pyroxene. Spherule cores are occasionally occupied by a corroded form of chromite. The chemical compositions of the kosmochlor exhibit a solid solution between kosmochlor (Ko98Jd0Ae1Q1) and jadeite (Ko25Jd61Ae6Q8). The maximum kosmochlor component is 98 mol.%, likely representing the closest known composition to the NaCrSi2O6 end-member, worldwide. Sodium amphiboles coexisting with kosmochloric pyroxene, and especially the cores of relatively large amphibole grains, in particular, contain high Cr2O3 (up to 12.2 wt.%, 1.34 apfu) and exhibit significant C-site deficiency (i.e., C-site cation < 5).

著者

Kenta Yoshida Rustam Orozbaev Takao Hirajima Akira Miyake Akira Tsuchiyama Apas Bakirov Akira Takasu Kadyrbek Sakiev

出版者

GEOCHEMICAL SOCIETY OF JAPAN

雑誌

GEOCHEMICAL JOURNAL (ISSN:00167002)

巻号頁・発行日

vol.52, no.1, pp.59-67, 2018 (Released:2018-02-02)

参考文献数

42

被引用文献数

5 5

---

Direct chemical analysis of a single fluid inclusion was conducted by micro-excavation at cryo-temperatures. A scanning electron microscope (SEM) equipped with a focused ion beam (FIB), an energy dispersive X-ray spectrometer (EDS), and a cold stage, were used to analyze the chemical composition of the sample fluid inclusion, which was trapped in the ultrahigh-pressure (UHP) talc-garnet-chloritoid schist obtained from the Makbal metamorphic complex, Kyrgyz. Conventional techniques such as microthermometry and cryo-temperature and room-temperature Raman spectroscopy enabled the detection of NaCl and CaCl2 as solute species in the fluid inclusions, as well as high salinity of 20.5 mass% CaCl2 and 1.7 mass% NaCl with the assumption of a NaCl-CaCl2-H2O ternary system. However, additional chemical analysis using the present cryo-FIB-SEM-EDS system further revealed the presence of K as a solute element, which is hardly identified by conventional techniques. Petrographic examination of the fluid inclusions indicated that they had been trapped during the exhumation stage of the UHP talc-garnet-chloritoid schist, possibly originating from the decompression breakdown of lawsonite. The data acquired from the present study challenges previous reports of the existence of simple chemical system of aqueous fluids in high-pressure and UHP metamorphic terrane in eastern Asia. This is imperative because misidentification of solute species introduces errors into salinity estimation, resulting in inaccuracy propagation in quantitative analytical processes such as LA-ICP-MS. A detailed fluid inclusion petrography would thus require accurate quantitative analysis involving FIB-based sample-preparation and SEM-EDS analysis.

著者

Adil KASYMBEKOV Akira TAKASU Md Fazle KABIR Shunsuke ENDO Apas B. BAKIROV Kadyrbek SAKIEV Rustam OROZBAEV Takao HIRAJIMA Kenta YOSHIDA

出版者

The Association for the Geological Collaboration in Japan

雑誌

地球科学 (ISSN:03666611)

巻号頁・発行日

vol.74, no.2, pp.47-64, 2020-05-25 (Released:2020-07-05)

参考文献数

43

---

キルギス北部天山に分布する高圧-超高圧変成作用を受けたマクバル・コンプレックス(Makbal Complex)中のネルディ層(Neldy Formation)のざくろ石を含まない泥質片岩(KG1251)と含ざくろ石-クロリトイド泥質片岩(KG1244)の岩石記載と地質年代の測定を行った.KG1251 の主要造岩鉱物はフェンジャイト,緑泥石と石英であり,その他に少量の曹長石,チタン石,方解石,ルチル及び炭質物を含む.ピーク変成条件はT < 630 ℃,P = 0.9-1.7 GPa が見積もられた.片理を形成するフェンジャイトのK-Ar 年代は524 ± 13 Ma であり,これはこれまでに報告されているマクバル・コンプレックスのエクロジャイト及びざくろ石-クロリトイド-タルク片岩のピーク変成年代(ca. 500 Ma)と調和的である.KG1244 の主要構成鉱物は白色雲母(コアがフェンジャイト,リムが白雲母),緑泥石,石英であり,その他に少量のざくろ石,クロリトイド,曹長石,電気石,ジルコン,モナザイト,チタン石,ルチル,方解石及び炭質物を含む.ピーク変成条件はT = 485-545 ℃,P = 1.2-1.5 GPa の高圧型変成作用を示し,その後,T = ca. 500 ℃,P > 0.3 GPa の低圧型変成作用を受けた.この変成作用は花崗岩体の貫入にともなう接触変成作用と考えられた.本研究で得られた白色雲母のK-Ar 年代(474 ± 12 Ma)は,この地域に分布するオルドビス紀の花崗岩の年代(ca. 460 Ma)と調和的である.KG1251 及びKG1244 のネルディ層の泥質片岩の変成条件は,マクバル・コンプレックスの構造・層序学的に下部を占めるエクロジャイトやざくろ石-クロリトイド-タルク片岩に比べて有意に低圧であることが明らかになった.