著者
Akira Suzuki Yasunori Yamamoto
出版者
(社)日本化学会
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
vol.40, no.9, pp.894-901, 2011-09-05 (Released:2011-09-05)
参考文献数
88
被引用文献数
145

The palladium-catalyzed cross-coupling reaction between different types of organoboron compounds and various organic halides or triflates in the presence of base provides a powerful and general methodology for the formation of carbon–carbon bonds. The Csp2–B compounds (such as aryl- and 1-alkenylboron derivatives) and Csp3–B compounds (alkylboron compounds) readily cross-couple with organic electrophiles to give coupled products selectively in high yields. Recently, the Csp–B compounds (1-alkynylboron derivatives) have been also observed to react with organic electrophiles to produce expected cross-coupled products. The overview of some of such coupling reactions is discussed here in this article.