- 著者
-
橋場 正男
廣畑 優子
日野 友明
新堀 寛
出山 貞夫
千代田 博宜
- 出版者
- 一般社団法人 日本真空学会
- 雑誌
- 真空 (ISSN:05598516)
- 巻号頁・発行日
- vol.42, no.12, pp.1100-1105, 1999-12-20
- 参考文献数
- 17
- 被引用文献数
-
1
The gas desorption properties of carbon based materials coated on inner wall of a cathode ray tube were examined by using a technique of thermal desorption spectroscopy (TDS). This material consists of graphite powder, titanium oxide (TiO<SUB>2</SUB>) powder and water glass. The major outgassing species observed in the temperature range from RT to 500°C were CO<SUB>2</SUB> and H<SUB>2</SUB>O. The major outgassing source was graphite. In order to reduce the gas desorption in the cathode ray tube, the heat treatment with temperature higher than 400-500°C is necessary.<BR>Since the surface morphology of graphite-water glass material was dense, the degassing was insufficient by baking treatment in the atmosphere. On the other hand, the degassing was very easy for graphite-TiO<SUB>2</SUB>-water glass material, because of the porous structure.<BR>The gas adsorption experiments were also conducted. The adsorption amount of H<SUB>2</SUB>O or CO<SUB>2</SUB> increased as the composition ratio of graphite powder. The gas adsorption capacity largely increased by the addition of TiO<SUB>2</SUB> powder into the graphite-water glass material. The enhancement of adsorption capacity is due to that the surface structure became porous and also the effective surface area large by the addition of TiO<SUB>2</SUB> powder.