著者

堀越 壮一 飯島 明宏 冨岡 淳 関 順司 加藤 政彦 小澤 邦壽

出版者

公益社団法人 日本水環境学会

雑誌

水環境学会誌 (ISSN:09168958)

巻号頁・発行日

vol.30, no.5, pp.283-286, 2007 (Released:2010-01-09)

参考文献数

28

被引用文献数

2 2

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Recently, nitrate-nitrogen (NO3-N) pollution in groundwater was identified as a serious problem in Gunma prefecture. The rate of satisfying the environmental quality standard(EQS) for NO3-N concentration in Gunma prefecture was lowest in Japan from 2000 to 2004. However, a significant decrease in NO3-N concentration was observed in 2005. Therefore, the factors contributing to the decrease were statistically examined. The results suggest that the area of dry field, livestock head count, and agricultural population significantly contributed to the decrease in NO3-N concentration. The enforcement of the Law on Promoting Proper Management and Use of Livestock Excreta might reduce NO3-N discharge into groundwater.

著者

山本 富久 中曽根 英雄 松沢 康宏 黒田 久雄 加藤 亮

出版者

公益社団法人 日本水環境学会

雑誌

水環境学会誌 (ISSN:09168958)

巻号頁・発行日

vol.27, no.5, pp.329-336, 2004-05-10 (Released:2008-01-22)

参考文献数

27

被引用文献数

1 1

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The water quality and discharge from a tea field area in Shizuoka were measured daily and the outflow loads of fertilizer components in runoff water estimated. The results are as follows: The amount of nitrogen fertilizer applied was about 1000kg·ha-1·yr-1 in the tea field. The annual of T-N effluent load from the tea field was 531kg·ha-1·yr-1 and it was 49% of the amount nitrogen fertilizer applied. 97% of the T-N load was composed of the NO3-N load. Its outflow load, which consisted of storm water, was 51%. The outflow NO2-N and NH4-N loads were small in the first half of the investigation period. The T-P outflow load from the tea field was 0.18kg·ha-1·yr-1 and the leaching rate was very low, at 0.05%. Most of the phosphate fertilizer was absorbed by the red-yellow soil in the tea field. The average T-P concentration was as low as 0.01 mg·l-1. However, the T-P concentration was very high after heavy rain in June and September of 2000. Storm water had a T-P outflow load concentration of 64%. The K+ outflow load was estimated to be 89kg·ha-1 for the year. The leaching rate was 14%. The percentage was very low because K+ was absorbed by surface soil containing clay minerals. The annual Mg2+ and Ca2+ outflow loads were 292kg·ha-1·yr-1 and 266kg·ha-1·yr-1, respectively. Their leaching rates were 63% and 26%, respectively.

著者

山本 富久 中曽根 英雄 松沢 康宏 黒田 久雄 加藤 亮

出版者

公益社団法人 日本水環境学会

雑誌

水環境学会誌 (ISSN:09168958)

巻号頁・発行日

vol.28, no.6, pp.399-404, 2005-04-10 (Released:2008-01-22)

参考文献数

51

被引用文献数

1 1

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The study area was located in the Makinohara collective tea fields in Shizuoka, Japan. There are flourishing tea industries in this area. The quality and level of the groundwater were observed from Jun. 2002 to Sept. 2003 and examined on the basis of hydrogeology. The Makinohara plateau comprises of clay layers between gravel beds. It yielded discontinuous water qualities caused by perched water in a geological structure. The average concentrations of T-N and NO3-N in the surface water were 26.4 mg·l-1, 23.8mg·l-1, respectively. In contrast, for the groundwater, these concentrations were 17.2 mg·l-1 and 12.6 mg·l-1, respectively. The average concentrations of T-P were 0.012 mg·l-1 in the surface water and 0.022 mg·l-1 in the groundwater. This difference is caused by the dilution effect and release of phosphorus from on aquifer. The annual groundwater effluent loads of nitrogen and phosphorus from the catchments of the Makinohara plateau were 406 t·y-1 and 0.7 t·y-1, respectively.

著者

臼井 恵次 進藤 晴夫 丸本 卓哉 岸野 拓男

出版者

公益社団法人 日本水環境学会

雑誌

水環境学会誌 (ISSN:09168958)

巻号頁・発行日

vol.17, no.9, pp.596-599, 1994-09-10 (Released:2008-01-22)

参考文献数

13

被引用文献数

2 1

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A release of phosphorus from calcium phosphate, iron(III) phosphate, and aluminum phosphate owing to the complex formation of their metals with fulvic acid was examined. Fulvic acid was extracted from lake sediments and treated with Amberlite XAD-8 resin. The non-adsorbed fraction of fulvic acid on the resin, which has highly Cu2+-complexing capacity, was used in this study, because the adsorbed fraction has only little Cu2+-complexing capacity as reported in our previous paper.The non-adsorbed fraction was able to release phosphorus from calcium phosphate, but not from iron(III) phosphate, and aluminum phosphate. The application of X-ray analysis to the calcium phosphate indicated that the major component is hydroxyapatite. The stability constant of the Cu2+-fractionated fulvic acid was determined to be 2×105 (log K=5.3) and the average molecular weight of the fulvic acid was 1,026.

著者

臼井 恵次 岸野 拓男 東 俊雄 進藤 晴夫 丸本 卓哉

出版者

公益社団法人 日本水環境学会

雑誌

水環境学会誌 (ISSN:09168958)

巻号頁・発行日

vol.16, no.10, pp.690-695, 1993-10-10 (Released:2008-04-21)

参考文献数

19

被引用文献数

5 3

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Fulvic acid extracted from lake sediments was treated with Amberlite XAD-2 and XAD-8 resins. The metal complexing ability of the fulvic acid was measured at pH 6.0 with a Cu2+ titration method, in which free Cu2+ was determined with an ion selective electrode. A two binding site model, in which there are two kinds of the molecules having strong and weak complexing ability and they complex with metal ion at the ratio of 1 : 1, was employed for the determination of the stability constant and complexing capacity of the fulvic acid, because the hyperbolic approxmation could apply to the Scatchard plot of the found values.The stability constants of the fulvic acids having strong complexing ability and weak complexing ability were in the range of 6.33-7.12 and 4.35-4.66, respectively. Both colorless fractions of the fulvic acid which were not adsorbed on XAD-2 and XAD-8 resins had such a high complexing ability as 44 and 32 μmol·g-1, respectively.On the other hand, both colored fractions of the fulvic acid which were adsobed on the resins had only little complexing capacity.

著者

中曽根 英雄 山下 泉 黒田 久雄 加藤 亮

出版者

公益社団法人 日本水環境学会

雑誌

水環境学会誌 (ISSN:09168958)

巻号頁・発行日

vol.23, no.6, pp.374-377, 2000 (Released:2006-12-01)

参考文献数

10

被引用文献数

15 16

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We found a special irrigation reservoir in which there are no algae, insects, or fish. Therefore, we have surveyed the water quality of an irrigation reservoir to find the reason for no living creatures. As the results of the survey, we found three factors such as high nitrate concentration, high aluminum concentration, and low pH value which will affect the lives of creatures in this irrigation reservoir. Among these three factors, the most important one is low pH in this irrigation reservoir. This low pH of the irrigation reservoir is derived from the overuse of nitrogen fertilizer at tea yards. About 1,000kg · ha-1 · y-1 of nitrogen fertilizer has been used to the tea yards for a long time. The remained nitrogen fertilizer which was not taken up by tea crop infiltrates through soils and enters into the ground water. This causes an over the Cation Exchange Capacity of soil and high aluminum concentration of this irrigation reservoir. To prevent this phenomenon from occurring, dozing lime under the root zone and reducing use of nitrogen fertilizer might be effective.