- 著者
-
阿部 英樹
佐藤 晃
- 出版者
- 公益社団法人 日本表面科学会
- 雑誌
- 表面科学 (ISSN:03885321)
- 巻号頁・発行日
- vol.34, no.3, pp.149-153, 2013-03-10 (Released:2013-03-22)
- 参考文献数
- 7
Japan is facing a challenge of wide-spread radioactive contamination by isotopes of cesium (Cs). Here we demonstrate that titanium oxide (TiO2) can be an efficient material to immobilize high concentrations of Cs ions in a durable solid-state framework. TiO2 was dissolved in a Cs-containing melt of molybdenum trioxide (MoO3) at 950oC. The melt was then electrolyzed at −1200mV (vs. a Pt reference electrode) to obtain a single-crystalline titanate, Cs0.169TiO2 (titanium-oxide immobilizer) , which contained 1g cm−3 of Cs. Moreover, the titanium-oxide immobilizer exhibited a 170 times lower Cs leaching rate than did Cs-containing borosilicate glass. The titanium-oxide immobilizer will contribute to the Cs decontamination because of its high Cs content and low Cs leaching.