著者

須藤 絢音 山口 潤一郎

出版者

公益社団法人 有機合成化学協会

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.79, no.10, pp.910-967, 2021-10-01 (Released:2021-10-08)

参考文献数

592

被引用文献数

4

---

Fluorination is a well-studied organic reaction due to widespread applications of fluorine compounds for pharmaceuticals. In this review, we focus on the monofluorination reactions reported in the past ten years and describe in detail about versatile types of C-F bonds in the products, with particular classification on the type of the reaction and the catalyst.

著者

須方 一明

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.39, no.1, pp.86-88, 1981-01-01 (Released:2009-11-13)

参考文献数

3

被引用文献数

4 4

---

The effects of polyethyleneglycol dialkyl ethers as solvents in the reaction of potassium 3-aminophenoxide with isopropyl chloride were studied. The reactions using the polyethyleneglycol dialkyl ethers as solvents gave O- isopropylated 3-aminophenol in higher yields than using small amounts of dibenzo-18- crown-6 or the polyethyleneglycol dialkyl ethers as solvents.

著者

杉原 博

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.39, no.1, pp.73-80, 1981-01-01 (Released:2010-04-23)

参考文献数

7

---

“Synthetic Methods of Organic Chemistry” by Theilheimer is well known as secondary sources of organic reactions. In 1975, a British company, Derwent published “Journal of Synthetic Method” as a part of Chemical Reactions Documentation Service (CRDS) system.On-line retrieval of CRDS by telephone line has been available in Japan and even Theilheimer can be retrieved on the same system. In addition to the above, in 1979, ISI published “Current Chemical Reactions” in U. S. A., thus secondary sources of organic reactions have been gradually developed.The present article reviews secondary sources which have seldom been reported before.

著者

森 謙治

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.39, no.1, pp.63-72, 1981-01-01 (Released:2009-11-13)

参考文献数

35

被引用文献数

4 6

---

Synthesis and biological activity of several chiral pheromones are discussed with emphasis on the synthetic strategies such as derivation from optically active natural products, optical resolution of intermediates and asymmetric synthesis using biochemical systems.

著者

有吉 安男

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.35, no.5, pp.369-374, 1977-05-01 (Released:2009-11-13)

参考文献数

55

被引用文献数

3 2

---

The phenomenon of taste is best explained by selective adsorption of taste stimuli onto a taste receptor. The sulfur-containing compounds taste sweet, sour, salty, or flavorous, depending on their chmical structures. The structure-taste relationships of sulfur-containing compounds, such as sugars, amino acids, peptides, sulfamic acids, saccharin derivatives, oxathiazinone dioxides, thioureas, and 5'-nucleotides, are discussed. The recent concept of the taste receptor sites is also described.

著者

矢田 登

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.38, no.3, pp.275-287, 1980-03-01 (Released:2009-11-13)

参考文献数

45

被引用文献数

1 1

---

Recent advances of prodrug formation of therapeutic agents were reviewed with 44 references in terms of (1) improvement of stability, (2) masking of bitter taste, (3) increase of water solubility, (4) improvement of bioavailability, and (5) selective distribution into the site of action.Basic consideration for rational design of prodrug was also presented.

著者

関屋 実

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.38, no.2, pp.176-181, 1980-02-01 (Released:2009-11-13)

参考文献数

15

被引用文献数

1 2

---

N- [(N-Nitrosoalkylamino) methyl] amides were recently reported from author's laboratory as new precursors for generating diazoalkanes. This review introduces N- [(N-nitrosoalkylamino) methyl] -carbamates and N- [(N-nitr osoalkylamino) methyl] benzamides as new diazoalkane-generating agents with their superiorities for practical use and stable diazoalkane-reagents, N, N-dialkyl-4-diazome-thylbenzenesulfonamides, prepared in this way, as new UV-detective labelling agents for acidic substances.

著者

山口 勝

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.38, no.1, pp.22-32, 1980-01-01 (Released:2009-11-13)

参考文献数

75

被引用文献数

1 2

---

The total synthesis of macrolides, a group of antibiotics having a variety of large lactone rings, has been one of the most important subjects in the recent synthetic elaborations on natural products. In the present review are described several new lactonization methods which have been used in the syntheses of this class of compounds and some new esterification methods developed in our laboratory, one of which, the method using the mixed carboxylic 2, 4, 6-trichlorobenzoic anhydrides, has been successfully applied to the synthesis of methynolide.

著者

杉 清明

出版者

社団法人 有機合成化学協会

雑誌

有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN (ISSN:00379980)

巻号頁・発行日

vol.63, no.6, pp.652-654, 2005-06-01

参考文献数

7

著者

森 裕二

出版者

公益社団法人 有機合成化学協会

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.79, no.9, pp.874-877, 2021-09-01 (Released:2021-09-08)

参考文献数

14

著者

岩間 雄亮 岡野 健太郎 徳山 英利

出版者

社団法人 有機合成化学協会

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.71, no.9, pp.926-934, 2013-09-01

参考文献数

35

被引用文献数

6

---

This review focuses on synthetic studies on mersicarpine that has a characteristic skeleton including seven-membered cyclic imine fused with indoline and δ-lactam. After a brief discussion of structural features and proposed biogenesis of this compound, several synthetic efforts toward construction of mersicarpine core are described. Total syntheses of mersicarpine are described including Kerr’s racemic synthesis utilizing a formation of seven-membered cyclic imine from α-hydroxyketone prepared by oxidation of indole, racemic syntheses of the Kerr’s synthetic intermediate by Zard and Han, the first enantiocontrolled total synthesis by Fukuyama based on the construction of seven-membered α-hydroxyimine by autoxidation of azepinoindole, and the second enantiocontrolled synthesis by Tokuyama employing a DIBALH-mediated ring-expansion reaction of cyclic ketoxime fused with indole.

著者

板谷 博

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.43, no.9, pp.891-896, 1985-09-01 (Released:2009-11-13)

参考文献数

8

被引用文献数

1 3

---

Oxalic acid is the simplest dicarboxylic acid formed by oxidation of organic compounds. Oxalic acid has been prepared by several methods in countries, because the industrial process depends on natural resouces, economical demands of the country, and chemical technology. This paper deals with its advantage and view points of each process ; oxidation of carbohyrates with nitric acid, thermal decomposition of sodium formate, two step oxidation of propylene, one step oxidation of ethyleneglycol, and the CO-coupling process, respectively.

著者

高岡 恒郎

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.24, no.5, pp.412-418, 1966-05-01 (Released:2010-06-28)

参考文献数

52

被引用文献数

2 5

著者

正田 晋一郎

出版者

公益社団法人 有機合成化学協会

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.79, no.8, pp.793-796, 2021-08-01 (Released:2021-08-07)

参考文献数

6

著者

宮崎 幸雄

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.42, no.10, pp.900-911, 1984 (Released:2009-11-13)

参考文献数

38

被引用文献数

1 2

---

The ionophorous antibiotics are a member of compounds possessing the ability to form complex with alkali ions and to carry ions across lipid barrier including artificial and biological membranes.These antibiotics have been employed as tools for studying properties of membrane-bound carriers as well as the molecular basis of biological ion discrimination. This report described the property of cation ionophores and some of biological applications of these substances.

著者

中村 薫 広瀬 芳彦

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.53, no.8, pp.668-677, 1995-08-01

被引用文献数

3 27

---

Recently, lipases are used widely as reagents for syntheses of chiral compounds, although organic chemists have only a little knowledge about characteristics of individual lipases. Reactivities and selectivities of lipase-catalyzed reactions are reviewed from a viewpoint of organic syntheses in the present article, which will be usefull for a guide to the proper selection of a lipase for kinetic resolutions of racemic compounds.

著者

小菅 卓夫 全田 浩

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.34, no.9, pp.612-624, 1976-09-01 (Released:2009-11-13)

参考文献数

88

被引用文献数

10 7

著者

中澄 博行 八木 繁幸

出版者

社団法人 有機合成化学協会

雑誌

有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN (ISSN:00379980)

巻号頁・発行日

vol.66, no.5, pp.477-487, 2008-05-01

参考文献数

52

被引用文献数

2

---

Novel bis-squaraine dyes have been synthesized in which two squaraine moieties are conjuga-tively linked by a methine group, thiophene, oligothiophene or arene spacer. New unsymmetrical squarylium dyes have been also prepared by condensation of mono-substituted squaric acid (semi-squaraine acid) with heterocyclic compounds with active methyl group or arylamines. These dyes exhibit large and intense absorption in the near-infrared region, and the X-ray structural analyses of these dyes show a planar structure. Semi-squaraine acids are key precursors for the synthesis of unsymmetrical squarylium dyes, and exhibited their absorption maxima at the shorter wavelength. Applications of squarylium dyes to photoconductive materials, photovoltatic devices, biological and environmental analysis are described. A Ca2+ ion-induced allostreic assem-bling of the squarylium dimmer was confirming by ESI-MS measurement showing the formation of metallo supramolecular complexes, that is the H-aggregate composed of at least three units.

著者

細田 豊

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.14, no.4, pp.234-239, 1956-04-01 (Released:2010-10-20)

参考文献数

10

著者

千畑 一郎

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.32, no.4, pp.286-297, 1974-04-01 (Released:2009-11-13)

参考文献数

79

被引用文献数

7 7