著者
夏井 俊悟 梨元 涼太 問谷 一偉 澤田 旺成 菊地 竜也 鈴木 亮輔
出版者
一般社団法人 資源・素材学会
雑誌
Journal of MMIJ (ISSN:18816118)
巻号頁・発行日
vol.135, no.8, pp.71-82, 2019-08-31 (Released:2019-08-27)
参考文献数
72
被引用文献数
1

The transient behavior of the multi-interfacial flow can be modeled using recent Smoothed Particle Hydrodynamics (SPH) model. This developed numerical method is fully-Lagrangian particle-based approach, which can track the movement of many fluid phase directly. The advantage of this simulation model is a direct calculation in both of dispersed phase and continuous phase seamlessly. Thereby this model estimates transient behavior of interfacial behavior by predicting the changes of each interface shape. For example, numerical simulations have been performed for different conditions corresponding to different values of surface tension, viscosity and density, and the predicted topological changes as well as the theoretical interfacial shape of droplets can be validated. Based on this model, we carried out relatively large-scale interfacial flow simulations, investigated case studies of metallurgical processing, and evaluated the non-steady state flow of formed from various dispersed phase.
著者
中村 大 川口 貴之 千葉 貴久 伊藤 陽司 渡邊 達也 山下 聡
出版者
一般社団法人 資源・素材学会
雑誌
Journal of MMIJ (ISSN:18816118)
巻号頁・発行日
vol.132, no.1, pp.14-21, 2016-01-01 (Released:2016-01-16)
参考文献数
5
被引用文献数
1

In this study, we conducted a follow-up survey of brick cracking on a brick wall in the parking space of JR Kitami Station and installed temperature sensors on the surface of the brick wall in order to measure changes in the brick wall temperature during late winter. In addition, we attempted to reproduce the brick cracking observed on the brick wall by conducting an indoor freeze-thaw experiment. The field investigation confirmed that the brick cracking on the brick wall occurred on the south-facing wall in the period from the coldest season to late winter. It was also confirmed from the records of the measured surface temperatures of the brick wall that, even in winter, the bricks could thaw in daytime and re-freeze at night, depending on the weather, solar radiation, and depth of snow coverage. Furthermore, we were successful in reproducing the brick cracking observed on the brick wall in the parking space of JR Kitami Station in the indoor freeze-thaw experiment. Our experience outlined above has demonstrated that frost damage can occur on the brick wall at JR Kitami station by a mechanism caused by the phenomenon of closed-system freeze-thaw, which the authors propose.
著者
林 良和 郭 柄霖 平島 剛 伊藤 竜也 中村 壮志 笹木 圭子
出版者
一般社団法人 資源・素材学会
雑誌
Journal of MMIJ (ISSN:18816118)
巻号頁・発行日
vol.135, no.7, pp.63-70, 2019-07-31 (Released:2019-07-31)
参考文献数
23

Removal of borate in mine drainages by co-precipitation with hydroxyapatite (HAp) was developed from a laboratory scale to a pilot scale. Weakly acidic initial pH facilitated to enhance dissolution of Ca(OH)2 and decrease the dissolved carbonate concentration, leading to efficient immobilization of borate and arsenate. The NH4H2PO4 lowered best the equilibrium B concentration among different phosphate sources, avoiding the lattice strain of HAp. The added molar ratio of P/Ca significantly influenced the decreasing behavior of the B concentration, showing the optimal value of 0.3. In case of P/Ca larger than 0.30, the excess concentration of PO43- was probably adsorbed on Ca(OH)2 particles to prevent the dissolution, resulting in inhibiting the formation of HAp. In case of P/Ca smaller than 0.30, the production of HAp was limited, leading to less immobilized borate. All the optimized conditions as above were applied to the pilot scale with a 250 L reactor, where borate concentration was effectively reduced in also both batch and continuous tests.
著者
西山 孝 安達 毅
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.109, no.6, pp.473-477, 1993-06-25 (Released:2011-01-27)
参考文献数
7
被引用文献数
2

World production of widely used metals grew rapidly until the early 1970's, as expressed in The Limits to Growth (Meadows et al., 1972), but then metal demand dropped sharply after 1973. Growth rates in production of each metal varied year by year or among metals.The difference between supply-demand forecast and actual production during last 20 years was examined. Different patterns between the two for 16 metals were classified into four groups.(1) The actual production of Co, Cr and Pt exceeded the projected trend that had been predicted in 1970.(2) Iron accounts for more than 95% of all metals consumed. A significant proportion of Mn, Ni, W, Mo, Cr and Co produced is used in the steel industry. This group, composed of iron and related metals other than Co and Cr, shows a similar pattern.(3) Growth rates of production of Cu, Zn, Ag, and Al continued to be low during the last 20 years, but the rates are not negative.(4) Growth rates of production of Pb, Au, Sn and Hg are negative or zero. Large differences between actual production and predicted consumption prevailed during the 1970-1990 period.When the lifetime of these metals calculated in 1970 are compared with those in 1990, static indices of Au, Hg, Ag, Sn, Zn and Pb which fall in the range of 10-30 year, have not changed very much. No tendency toward depletion of the resources has been found under the present condition. New reserves have been discovered in the last 20 years. A basic question in the long-term supply is how long the present situation continue.
著者
臼井 進之助 佐々木 弘
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.107, no.9, pp.585-591, 1991-08-25 (Released:2011-01-27)
参考文献数
71
被引用文献数
2 4
著者
福井 勝則 大久保 誠介 寺嶋 卓文
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.117, no.9, pp.703-710, 2001 (Released:2006-01-08)
参考文献数
21
被引用文献数
1 2

A number of studies on electromagnetic wave emission from fractured rocks have been heretofore carried out. By many authors it was pointed out that rock fracturing or acoustic emission could be concerned with electromagnetic wave emission. However, the origin of electromagnetic wave emission is still not well understood.In this study electromagnetic wave from rocks was measured with a radio interference measuring apparatus during uniaxial compression testing under several kinds of loading conditions.Firstly, the uniaxial compression testing under constant strain rate of 10-4 s-1 was conducted for seven rocks. It was found that Inada granite, Honkomatsu andesite and Kuzuu dolomite emit electromagnetic wave. However electromagnetic wave cannot be detected for Sanjome andesite, Akiyoshi marble, Kimachi sandstone and mortar.Secondly, electromagnetic wave emission was investigated under several experimental conditions. It was found that Inada granite emits electromagnetic wave during uniaxial compression testing under a constant strain rate of 10-5 s-1 and under a constant rate of (stress-strain / Young's modulus).In most cases, electromagnetic wave emission was accompanied with sudden decrease of stress. By analysis on results of the uniaxial compression testing under constant strain rate, it was found that electromagnetic wave emission is closely related to cracking or crack extension.The main results in this study can be summarized as follows;1) Amplitude of electromagnetic wave is relatively large for strong rock.2) For Inada granite, the larger the stress drop occurred in uniaxial compression test is, the larger the amplitude of electromagnetic wave.
著者
片岡 みなみ 尾原 祐三 Leona VAVRO Kamil SOUCEK Sang-Ho CHO Sang-Sun JEONG
出版者
一般社団法人 資源・素材学会
雑誌
Journal of MMIJ (ISSN:18816118)
巻号頁・発行日
vol.135, no.5, pp.33-41, 2019-05-31 (Released:2019-05-25)
参考文献数
32
被引用文献数
5

岩石のモードI破壊靭性を評価するための試験法がこれまでに数多く提案されてきているが,同じ岩石の破壊靭性を異なった試験法で評価し,得られた結果が比較されることはまれである。このため,破壊靭性に及ぼす試験法の違いが明らかにされているとは言い難い。また,岩石の破壊靭性は試験法の違いだけでなく,用いる供試体寸法によっても影響を受けると考えられる。これらの影響を明らかにするために,様々な破壊靭性試験が行われてきた。しかし,これまでの実験では,同じ岩石で作製された供試体数が十分でなかったり,あるいは供試体寸法の違いの範囲が狭かったために,それらの影響を明らかにするまでに至っていないと考えられる。 本論文では,来待砂岩を供試体として用い,3種類の破壊靭性試験法,すなわち,CB試験,SCB試験およびSNDB試験を実施し,破壊靭性に及ぼす試験法の影響を検討するとともに,半径12.5mm〜150mmの範囲の供試体を用いたSCB試験を実施し,供試体寸法の影響を検討した。この結果,CB試験とSCB試験による破壊靭性はほぼ同等の結果を得ることができたが,SNDB試験の破壊靭性はそれらの値より小さく評価されることを示した。また,供試体寸法が大きくなるとともに破壊靭性も増大することを明らかにした。
著者
音藤 実雄
出版者
一般社団法人 資源・素材学会
雑誌
日本鉱業会誌 (ISSN:03694194)
巻号頁・発行日
vol.77, no.878, pp.546-560, 1961-08-25 (Released:2011-07-13)
参考文献数
17

Our Sorachi Mine situated in the northern part of the Ishikari Coal-Field in Hokkaido was opened for mining in 1890. Since then, we applied many systems of mine opening...such as drift from outcrop, the gallery entry, the shallow shaft, the steep shaft, and the incline method, Up to 1957, both three inclines let out only 800-900 tons per day, and then the coal reserves available, had only three years in a life of exploitation.The output production plan was decided in the maximan of 1600tons per day withoutincreasing the capacity of the washing plant and the National Railway. Due to the housing and water ways problems, it was impossible to increase the number of workers.In order to double the output total, it was either to increase the output per man shift at the face. cut (1), or decrease the number of indirect workers and transfer them to the face cut (2). In these two ways, the latter was decided by the reason that geological conditions were too complex and difficult to adapt the first way.Then a plan with a capital investment of 1600 millions yens was carried out. A speedy opening by a new field was struggled by means of:(1) Reconstruction of mine structure (Horizontal mining system)(2) Adoption of permanent spports(3) Synchronized rationalization of transportation (by automation and remote control)(4) As well as modernization and intensification of pitmouth equipment installations In three years time, from May 15, 1957 to. May 13, 1960 and with 390, 000 workers, the construction works were completed according to a plans.As a result, the output per day was increased from 839 tons average in 1959 to 1154 tons in January 1961, just 8 months after the completion. And the output per man-month was increased from 18.4 tons to 28.6 tons.And the man-powers per 100 tons of output in the face working was reduced to 38. 0 M. S, . in the indirect working 23.9 M.S.and in the under ground working 61.9 M. S. after all. While, the man-powers in the surface working was reduced to 17.4 M. S. These productivities of labour are already near the levels in the Wester Europe.
著者
佐藤 康晴 清野 文雄 小笠原 啓一 山本 佳孝 佐藤 徹 平林 紳一郎 清水 賀之
出版者
一般社団法人 資源・素材学会
雑誌
Journal of MMIJ (ISSN:18816118)
巻号頁・発行日
vol.129, no.4, pp.124-131, 2013-04-01 (Released:2014-04-14)
参考文献数
20
被引用文献数
5 9

The motion of a single MH-bubble in quiescent fluid was examined experimentally. If a methane-gas bubble is placed under the condition that hydrates nucleation can initiate, typically at high pressure and low temperature, a thin methane hydrate film is formed on the bubble surface and it alters the motion of the bubble in the fluid drastically. It behaves as if solid did.To clarify the fluid dynamics of MH-bubbles, we devised the special apparatus which enabled us to observe the three dimensional behaviours of the MH-bubbles under high pressure condition. The three dimensional motions of the MH-bubbles were captured by two high-speed cameras whose resolution was 1024*1024 pixel at 500Hz. To analyze the motions of the MH-bubbles, Direct Linear Transformation Method was adopted.Equivalent diameter of the MH-bubble was altered from 3.8 to 7.8 mm, which corresponded to the range from 555 to 1155 in Reynolds number, by replacing the nozzles with different diameters.The MH- bubbles in this range exhibited the zigzag motion, while methane bubbles the spiral motion. Main findings in this research are as follows:(1) The aspect ratio, the height to width ratio, decreased linearly with the increment of the equivalent diameter of a MH-bubble. This reflects the fact that the shape of the MH-bubble shifts from spherical to ellipsoidal. (2) Strouhal number which characterizes the zigzag motion of the MH-bubbles increased with Reynolds number. (3) The drag coefficients were measured up to the Reynolds number of about 1000. The drag coefficient of a MHbubble departs from the standard drag curve when the shape deformation become notable. After that, it rise in accordance with the progress of the deformation. These phenomena also have been observed in the behaviour of a bubble with a surfactant.
著者
李 孝淑 康 南基 呉 在賢
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.110, no.4, pp.297-302, 1994-04-25 (Released:2011-08-04)
参考文献数
9
被引用文献数
2 2

水溶液中における磁鉄鉱生成の機構を明らかにするために, 本報では先ずFe (OH) 2懸濁液の酸化条件による磁鉄鉱生成の速度ならびに生成粒子に関して調べた。それからFe (OH) 2懸濁液に三価鉄を理論量だけ加えると粒径100Å前後の磁鉄鉱が瞬間的に生成されることがわかった。Fe (OH)2とFe(OH)3の適定試験における溶液の色の変化ならびに適定曲線と三価鉄の影響をあわせ考え次のような固体-固体反応による磁鉄鉱の生成機構を導出した。Fe (OH)2(s)+2Fe(OH)3(s)→Fe3O4 (s)+4H2O
著者
三上 博史 周 伝久 高橋 千一郎 佐藤 忠夫 嶋影 和宜
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.110, no.4, pp.313-318, 1994
被引用文献数
2

Vanadium diboride (VB<SUB>2</SUB>) film has been synthesized on mild steel and transparent quartz substrates by CVD method, which was carried out at the temperature range of 1073 to 1223K with the hydrogen reduction of VOCl<SUB>3</SUB>-BCl<SUB>3</SUB> mixture under the chemical erquivalent ratio regions of 10 to 40 for H<SUB>2</SUB>-VOCl<SUB>3</SUB> gases and of 40 to 120 for H<SUB>2</SUB>-BCl<SUB>3</SUB> gases. VB<SUB>2</SUB> film involving both Fe<SUB>2</SUB>B and FeB was synthesized on a mild steel substrate because a mild steel plate was borided with BCl<SUB>3</SUB> gas. On the other hand, pure VB<SUB>2</SUB> layer film was prepared on a transparent quartz substrate atthe temperature above 1173K. Futhermore, VB<SUB>2</SUB> film having high orientation and crystallization could not be prepared on a mild steel substrate. However, smooth surface VB<SUB>2</SUB> film having high crystallization and micro-vickers hardness of about 2800Hmv could be synthesized on a transparent quartz substrate at the temperature of 1173K under the conditions of chemical equivalent ratio of 40 for H<SUB>2</SUB>-VOCl<SUB>3</SUB> gases and of 80 for H<SUB>2</SUB>-BCl<SUB>3</SUB> gases.
著者
山口 勉功 棚橋 満 月橋 文孝 長崎 英範 服部 靖匡 大石 敏雄
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.119, no.10,11, pp.683-686, 2003 (Released:2006-04-05)
参考文献数
63
被引用文献数
2

Recently, several removal technologies of minor elements in copper smelting have been developed along with the degradation and the diversification of copper concentrates and also for assuring the quality of cathode. This article reviews the current and new elimination technologies of minor elements for copper smelting based on the recently published papers focusing specifically on arsenic, antimony, bismuth, lead and nickel among various impurities. In this article, the removal technologies in copper smelting are classified into five categories; (1) pre-treatment, (2) extraction from matte or copper, (3) dust treatment, (4) anode doping and (5) purification of electrolyte. Vacuum refining which is not established as a current industrial process is also described in this article.
著者
武山 詳 坂口 清敏 渡邉 則昭 土屋 範芳
出版者
一般社団法人 資源・素材学会
雑誌
Journal of MMIJ (ISSN:18816118)
巻号頁・発行日
vol.135, no.3, pp.25-30, 2019-03-31 (Released:2019-03-29)
参考文献数
26

Gypsum aggregate specimens have been used in the present study, because brittle, semi-brittle and ductile stress-strain behaviors of the specimen can be controlled only with confining stress level at the room temperature. At confining stresses up to 40 MPa, tri-axial compression and fluid flow experiments have been conducted on the intact specimens and single fracture specimens. It has been indicated that stress-strain behavior is independent of existence of fracture. Moreover, permeability of the single fracture specimen is much higher than intact specimen at conditions of brittle, semi-brittle, intermediate state between semi-brittle and ductile and ductile condition. On the other hand, permeability of the single fracture specimen is not so different from that of the intact specimen at conditions of a transitional behavior between semi-brittle and ductile stress-strain behaviors. As for the geothermal reservoir in the semi-brittle and ductile region, it was suggested that the fracture is retained and permeability is maintained when fracturing occurs due to hydraulic crushing or the like.
著者
小林 哲 隅田 洋
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.109, no.12, pp.1087-1090, 1993-12-25 (Released:2011-01-27)

Takehara Plant of MMS is located in the city center of Takehara, near the National Park of Seto Inland Sea. At present, 40 different products are manufactured at our plant, including non-ferrous metals, various battery materials and chemical products.Commercial production of Electrolysis Manganese Dioxide (EMD), begun in 1949, was small about 5 ton/month, and the plant was gradually expanded so that it had a monthly capacity of 2, 100 tons in 1982.Our EMD is specifically used for ZnC12, Alkaline and Lithium batteries, therefore EMD's high quality is very important. In this paper, the outline of our process and improvement in our plants and quality are described.
著者
畠山 信夫 清水 賀之 益山 忠
出版者
一般社団法人 資源・素材学会
雑誌
Journal of MMIJ (ISSN:18816118)
巻号頁・発行日
vol.135, no.2, pp.15-24, 2019-02-28 (Released:2019-02-28)
参考文献数
16
被引用文献数
1

The rheological properties of cement slurries (including fresh concrete and high concentration paste for filling etc.) are complicated, therefore they are approximated by the Bingham plastic model. In recent years, the application of Herschel-Bulkley model is recommended for drilling mud. The rheological coefficients of these models are obtained by using measurement results of the rotational viscometer or experimental results of the flow in a circular pipe, and the pressure loss in pipe flows is obtained from these rheological coefficients. Therefor it is essential to properly select the model in order to design the slurry transportation. In the field of well drilling, the flow in a concentric annulus with a relatively large pipe diameter ratio is approximated by the flow in a parallelplate, so it is also necessary to consider the flow in a parallel-plate. In this study, first, a method to determine the rheological coefficients by the least squares method from measurement results of the rotational viscometer using the function provided in a spreadsheet is shown and a method to quantitatively select the rheological model using Akaike's information criterion is also shown. Next, after the exact solutions of flows in a circular pipe and in a parallel-plate is summarized, an approximate expression of wall shear stress is derived and the error analysis is performed, and its effectiveness is confirmed by using past experimental data. In addition, a method of calculating the rheological coefficients by the least squares method from measurement results of flows in a circular pipe and in a parallel-plate using spreadsheet is shown and this method is practiced by using the experimental data of the flow in pipes.
著者
島田 昌彦
出版者
一般社団法人 資源・素材学会
雑誌
資源と素材 (ISSN:09161740)
巻号頁・発行日
vol.111, no.2, pp.67-69, 1995-02-25 (Released:2011-01-27)
参考文献数
6

Characteristics of high fracture strength and high fracture toughness of zirconia in yttria doped tetragonal zirconia polycrystal (Y-TZP), Y-TZP/Al2O3 composites and ceria doped tetragonal zirconia polycrystal (Ce-TZP) are described in this paper. The maximum fracture strength of Y-TZP/Al2O3 composites is 2, 400MPa at 30°C The maximum fracture toughness of Ce-TZP is 20 MPam1/2It is found that hot isostatic pressing is effective to eliminate fracture origins such as pore. From the results of thermal shock behavior of Y-TZP with various grain sizes by the water quenching method and the tetragonal to monoclinic phase transformation by using Raman microprobe spectroscopy, it is found that the critical quenching temperature different of Y-TZP increases from 250°C to 425°C with increasing grain size from 0.4 to 3.0μm.